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tetrasulfur tetranitride formula

The SensagentBox are offered by sensAgent. Meaning of tetrasulfur tetranitride. [1] The bonding in S4N4 is considered to be delocalized, which is indicated by the fact that the bond distances between neighboring sulfur and nitrogen atoms are almost the same. To make squares disappear and save space for other squares you have to assemble English words (left, right, up, down) from the falling squares. The anion NS4− has a chain structure described using the resonance [S=S=N-S-S]− ↔ [S–S–N=S=S]−. "Preparation and Crystal Structure of [(AlBr, an offensive content(racist, pornographic, injurious, etc. S4N4 adopts an unusual “extreme cradle” structure, with D2d point group symmetry. [11][12] In addition, adducts of aluminium chloride with Se2N2 have been isolated, this is formed from Se4N4.[13]. [13], The selenium compound Se4N4 is known and has been the subject of some research. The {[(CH3)3Si)2N]2S} reacts with the combination of SCl2 and SO2Cl2 to form S4N4. This endothermic enthalpy of formation anticipates its inherent instability, and originates in the difference in energy of S4N4 compared to its highly stable decomposition products: Although many complex molecules are unstable in a thermodynamic sense yet stable kinetically, this is uncommon for very simple compositions, such as sulfur nitride. Indeed, a large number of S-N and S-NH compounds are known with S4N4 as their parent. S4N4 adopts an unusual “extreme cradle” structure, with D2d point group symmetry. [1], Until recently, S4N4 was prepared by the reaction of ammonia with SCl2 in carbon tetrachloride followed by extraction into dioxane. This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. Formula/name Common name Other names Notes S 2: disulfur: A diatomic gas with a triplet ground state like dioxygen. This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. Tips: browse the semantic fields (see From ideas to words) in two languages to learn more. S4N4 is thermochromic, changing from pale yellow below -30 °C to orange at room temperature to deep red above 100 °C. The soft Lewis acid CuCl forms a polymer containing intact S4N4 rings as the bridging ligands:[1], S4N4 is sensitive to hydrolysis in the presence of base. Silicon tetrafluoride and tetrasulfur tetranitride. Tetrasulfur pentoxide S4N4 So, prefix di is used. It can be viewed as a derivative of a hypothetical eight-membered ring of alternating sulfur and nitrogen atoms. In the conversion, the silver first becomes sulfided, and the resulting Ag2S catalyzes the conversion of the S4N4 into the four-membered ring S2N2, which readily polymerizes. It can be viewed as a derivative of a hypothetical eight-membered ring of alternating sulfur and nitrogen atoms. This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. 28950-34-7 - LTPQFVPQTZSJGS-UHFFFAOYSA-N - Tetrasulfur tetranitride - Similar structures search, synonyms, formulas, resource links, and other chemical information. Mol. [5], Until recently, S4N4 was prepared by the reaction of ammonia with SCl2 in carbon tetrachloride followed by extraction into dioxane, producing sulfur and ammonium chloride as side-products:[6], A related synthesis employs sulfur monochloride and NH4Cl instead:[1]. Disulfur tetranitride is the chemical name of the molecular formula S4N4. The [((CH3)3Si)2N]2S reacts with the combination of SCl2 and SO2Cl2 to form S4N4, trimethylsilyl chloride, and sulfur dioxide:[7], S4N4 serves as a Lewis base by binding through nitrogen to strongly Lewis acidic compounds such as SbCl5 and SO3. ... Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. Silicon tetrachloride- SiCl4 Burt, who obtained it by heating tetrasulfur tetranitride in vacuum over silver wool.. This entry is from Wikipedia, the leading user-contributed encyclopedia. Chemistry Chemistry for Engineering Students 2.63 Write the molecular formula for each of the following covalent compounds: (a) sulfur hexafluoride, (b) bromine pentafluoride, (c) disulfur dichloride, (d) tetrasulfur tetranitride. English Encyclopedia is licensed by Wikipedia (GNU). [S4N5]+. Company Information It may not have been reviewed by professional editors (see full disclaimer), All translations of Tetrasulfur tetranitride. With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter. [9] Reaction with piperidine generates [S4N5]−: It is indicative of the richness of this area that a related cation is also known, i.e. A windows (pop-into) of information (full-content of Sensagent) triggered by double-clicking any word on your webpage. Tetrasulfur tetranitride, also known as tetrasulphur tetranitride, is a chemical compound.Its chemical formula is S 4 N 4.It contains sulfur in its +3 oxidation state.It also contains nitride ions. Contact Us S4N4 is thermochromic, changing from pale yellow below −30 °C to orange at room temperature to deep red above 100 °C. Indeed, a large number of S-N and S-NH compounds are known with S 4 N 4 as their parent. [5], S4N4 serves as a Lewis base by binding through nitrogen to strongly Lewis acidic compounds such as SbCl5 and SO3. "Reaction of Tetrasulfur Tetranitride with Sulfuric Acid". S4N4 reacts with Vaska's complex ([Ir(Cl)(CO)(PPh3)2] in an oxidative addition reaction to form a six coordinate iridium complex where the S4N4 binds through two sulfur atoms and one nitrogen atom. [4], A related synthesis employs NH4Cl in place of ammonia:[1]. Expert Answer 100% (1 rating) Previous question Next question ), Journal of the Chemical Society, Perkin Transactions 2, http://en.wikipedia.org/w/index.php?title=Tetrasulfur_tetranitride&oldid=503332447, 1,3,5,7-tetrathia-2,4,6,8-tetraazacyclooctan-2,4,6,8-tetrayl. Most English definitions are provided by WordNet . The cage is distorted in these adducts, thus delocalization of electrons may be disrupted.[1]. formula: N4Si3 Hazard classification & labelling According to the notifications provided by companies to ECHA in REACH registrations no hazards have been classified. To use all the functions on Chemie.DE please activate JavaScript. [8], Passing gaseous S4N4 over silver metal yields the low temperature superconductor polythiazyl or polysulfurnitride (transition temperature (0.26±0.03) K[9]), often simply called "(SN)x." Your browser does not support JavaScript. The symbol Se represents selenium. Question: Write The Formula For Each Of The Following Covalent Compounds. It contains sulfur in its +3 oxidation state. Boggle gives you 3 minutes to find as many words (3 letters or more) as you can in a grid of 16 letters. Tetrasulfur Tetranitride (S4N4) DETONATION VELOCITY: 5.4 - 5.6 km/sec SENSITIVITY: Very sensitive to friction great care would be needed to produce this compound. [1], S4N4 has been shown to co-crystallize with benzene and the C60 molecule. The pairs of sulfur atoms across the ring are separated by 2.586 Å, resulting in a cage-like structure as determined by single crystal X-Ray diffraction. Get XML access to fix the meaning of your metadata. M.; Litvinov, A. L.; Semkin V. N.; Tarasov, B. P. (2000). S4N4 reacts with electron-poor alkynes. Answer: Tetrasulfur Dinitride S4N2. It is protonated by HBF4 to form a tetrafluoroborate salt: The soft Lewis acid CuCl forms a polymer containing intact S4N4 rings as the bridging ligands:[1], S4N4 is sensitive to hydrolysis in the presence of base. MOLECULAR FORMULAS. Read what you need to know about our industry portal chemeurope.com. 1 mole is equal to 1 moles Tetrasulfur Tetranitride, or 184.2868 grams. This problem has been solved! The reaction of S4N4 with the [Pd2Cl6]2− anion forms a series of three palladium complexes in which the S4N4 ring has been fragmented. Treatment with tetramethylammonium azide produces the heterocycle [S3N3]−: In the language of electron counting, [S3N3]− has 10 pi-electrons: 2e−/S plus 1e−/N plus 1e− for the negative charge. Bojes, J.; Chivers, T; Oakley, R. D.; Rauchfuss, T. B.; Gammon, S. (1989). The second element is oxygen and it is named by its root −ox by adding −ide. Predicted data is generated using the US Environmental Protection Agency’s EPISuite™. This . The cage is distorted in these adducts, thus delocolization of electrons may be disrupted.[1]. The SI base unit for amount of substance is the mole. bp 760 ~185°. Lettris is a curious tetris-clone game where all the bricks have the same square shape but different content. Bojes, J.; Chivers, T; Oakley, R. D.; Womershäuser, G.; Schnauber, M. (1989). This compound arises by the formal breaking of one S-N bond in the oxidative addition, followed by the coordination of the lone pair on another sulfur atom to form a dative bond. 0 1 2 write formula for following compounds. You can also try the grid of 16 letters. [3] The nature of the "transannular" S–S interactions remains a matter of investigation because it is significantly shorter than the sum of the van der Waal's distances[4] but has been explained in the context of molecular orbital theory. Small samples can be detonated by striking with a hammer. [11], Passing gaseous S4N4 over silver metal yields the low temperature superconductor polythiazyl or polysulfurnitride (transition temperature (0.26±0.03) K[12]), often simply called "(SN)x". Find out more, Sharma, B. D.; Donohue, J. Nitrogen and sulfur have similar electronegativities. Molecular weight calculation: 32.065*4 + 14.0067*4 ›› Percent composition by element … "Caged explosives: Metal-Stabilized Chalcogen Nitrides". The pairs of sulfur atoms across the ring are further bonded, resulting in a cage-like structure with pentagonal S3N2 rings. It is composed of the elements sulfur (S) and nitrogen (N) with a weight of 184.3 grams per mole. "The Reactivity of Se, Kelly, P. F.; Slawin, A. M. Z.; Soriano-Rama, A. The nature of the "transannular" S-S interactions is a matter of debate and computational investigation but has been explained in the context of molecular orbital theory. "The Crystal and Molecular Structure of Sulfur Nitride, S. Jolly, W. L.; Lipp, S. A. Because one of its decomposition products is a gas, S4N4 is an explosive. Nitrogen and sulfur have similar covalently bonded structures. This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen. With a SensagentBox, visitors to your site can access reliable information on over 5 million pages provided by Sensagent.com. S4N4 is shock-sensitive, thus grinding solid samples should be avoided.  | Last modifications, Copyright © 2012 sensagent Corporation: Online Encyclopedia, Thesaurus, Dictionary definitions and more. See the answer. (noun) Choose the design that fits your site. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. Find out how LUMITOS supports you with online marketing. "Superconductivity in Polysulfur Nitride (SN), Konarev, D. V.; Lyubovskaya, R. N.; Drichko, N. V.; Yudanova, E. I.; Shulga, Yu. All rights reserved. Small samples can be detonated by striking with a hammer. Each square carries a letter. It also contains nitride ions. SeO2 - Selenium dioxide S4N4 - tetrasulfur tetranitride PBr3 - phosphorus tribromide. Tetrasulfur pentoxide S4N4. Purer samples are reportedly more sensitive than those contaminated with elemental sulfur. (chemistry) The allotrope of sulfur, S4 having four atoms in a ring. Many important S-N compounds are prepared from S4N4. It is, however, unstable in the thermodynamic sense with a positive enthalpy of formation of +460 kJ mol−1. This combination of kinetic stability and thermodynamic instability is, however, uncommon for very simple compositions, such as sulfur nitride. [1] Purer samples tend to be more explosive. Many important S-N compounds are prepared from S4N4. ○   Boggle. Its chemical formula is S 4 N 4. "Donor-Acceptor Complexes of Fullerene C, Kelly, P. F.; Woollins, J. D. (1993). The reaction of S4N4 with the [Pd2Cl6]2- anion forms a series of three palladium complexes in which the S4N4 ring has been fragmented. The first element of this molecule is Se, so, its name is written first. Sulfur forms a variety of covalent binary nitrides, but the two most interesting ones are tetrasulfur tetranitride, S 4 N 4, and disulfur dinitride, S 2 N 2, because they are precursors to an unusual polymer called polythiazyl, (SN) x. The mass and molarity of chemical compounds can be calculated based on the molar mass of the compound.  |  Letters must be adjacent and longer words score better. Write the formula for each molecule: Silicon tetrachloride Boron tetrafluoride Chlorine monoxide. tetrasulfur tetranitride magnesium phosphide copper(I) bisulfite . S4N4 adopts an unusual “extreme cradle” structure, with D2d point group symmetry. Properties: Orange-red, monoclinic needles from benzene, mp 178°. Typically, a molecular formula begins with the nonmetal that is closest to the lower left corner of the periodic table, except that hydrogen is almost never written first (H 2 O is the prominent exception). The compound was first reported as early as 1910 by F.P. Molar Mass: 184.2868 This compound arises by the formal breaking of one S-N bond in the oxidative addition, followed by the coordination of the lone pair on another sulfur atom to form a dative bond. Reactions of S4N4 where the ring remains intact, Reactions of S4N4 where the ring does not remain intact, S4N4 as a precursor to other S-N compounds, Wikipedia article "Tetrasulfur_tetranitride". Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1.67 estimate) = 2.63 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.42): Boiling Pt (deg C): 655.53 (Adapted Stein & Brown method) Melting Pt (deg C): 285.25 (Mean or Weighted MP) VP(mm Hg,25 deg C): 3.34E-015 (Modified Grain … See if you can get into the grid Hall of Fame ! Tetrasulfur tetranitride is an inorganic compound with the formula S 4 N 4.This gold-poppy coloured solid is the most important binary sulfur nitride, which are compounds that contain only the elements sulfur and nitrogen.It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding. The web service Alexandria is granted from Memodata for the Ebay search. Z.; Zingaro, R. A. Tetrasulfur tetranitride N4S4. References The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following. Kelly, P. F.; Slawin, A. M. Z.; Williams, D. J.; Woollins, J. D. (1992). Add new content to your site from Sensagent by XML. (1996). [14][15] In addition, adducts of aluminium chloride with Se2N2 have been isolated; this is formed from Se4N4.[16]. TetraSulfur TetraNitride crystallizes in orange-red needles which melt at 178degC. S4N4 is shock-sensitive, thus grinding solid samples should be avoided. The mass (in grams) of a compound is equal to its molarity (in moles) multiply its molar mass: grams = mole × molar mass. Nitrogen and sulfur have similar electronegativities, which is the ability to attract electrons. ○   Anagrams The reaction of [Pt2Cl4(PMe2Ph)2] with S4N4 is reported to form a complex where a sulfur forms a dative bond to the metal, this compound upon standing is isomerised to a complex in which a nitrogen atom forms the additional bond to the metal centre. It is, however, unstable in the thermodynamic sense with a positive heat of formation of 460 kJ/mol). To use all functions of this page, please activate cookies in your browser. By using our services, you agree to our use of cookies. (1967). Dilute NaOH hydrolyzes S4N4 as follows:[1]. [S4N5]+. tetrasulfur tetranitride, S4N4, and disulfur dinitride, S2N2, because they are precursors to an unusual polymer called polythiazyl, (SN)x. Change the target language to find translations. Convert grams Tetrasulfur Tetranitride to moles or moles Tetrasulfur Tetranitride to grams. Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. InChI=1S/N4S4/c1-5-2-7-4-8-3-6-1 Y A more recent synthesis entails the use of [(Me3Si)2N]2S as a precursor with pre-formed S–N bonds. (1971). Dilute NaOH hydrolyzes S4N4 as follows, yielding thiosulfate and trithionate:[1]. [1] Purer samples tend to be more explosive. ›› Tetrasulfur Tetranitride molecular weight. ○   Lettris Small quantities (less than one gram) deflagrate with a poof and larger sizes will detonate. In an apparently related reaction, the use of PPN+N3 gives the blue perthionitrite salt: The anion NS3- is a chain described often as S=N-S-S-. Treatment with tetramethylammonium azide produces the heterocycle [S3N3]-: In the language of electron counting, [S3N3]- has 10 pi-electrons: 2e-/S plus 1e-/N plus 1e- for the negative charge. What does tetrasulfur tetranitride mean? (1975). [1], S4N4 has been shown to co-crystallize with benzene and the C60. © 1997-2020 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Tetrasulfur_tetranitride.html, Your browser is not current. Key: LTPQFVPQTZSJGS-UHFFFAOYSA-N Y, Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. The pairs of sulfur atoms across the ring are further bonded, resulting in a cage-like structure with pentagonal S3N2 rings. Ro, Cookies help us deliver our services. Solubility: soluble in … When atoms are so evenly matched, they often form extensive families of covalently bonded structures. [1], S4N4 was first prepared in 1835 by W. Gregory, by the reaction of sulfur monochloride with ammonia. Name the following: SeO2 S4N4 PBr3. The bonding in S4N4is c… History. When atoms are so evenly matched, they often form extensive families of covalently bonded structures. [7] Reaction with piperidine generates [S4N5]−: It is indicative of the richness of this area that a related cation is also known, i.e. Xenon Hexafluoride Selenium Dichloride Silicon Tetrachloride Arsenic Pentafluoride Dinitrogen Tetroxide Tetrasulfur Tetranitride Disulfur Heptoxide Carbonic Acid Give The Name … Question: Write Formula For Following Compounds Silicon Tetrafluoride And Tetrasulfur Tetranitride. The English word games are: ; Chivers, T; (2002). It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding.[1][2]. Whereas more concentrated base yields sulfite: S4N4 reacts with Vaska's complex ([Ir(Cl)(CO)(PPh3)2] in an oxidative addition reaction to form a six coordinate iridium complex where the S4N4 binds through two sulfur atoms and one nitrogen atom. A related Pt(IV) compound arises from Zeise's salt. Tetrasulfur tetranitride is an inorganic compound with the formula S4N4. Tetrasulfur Tetranitride S4N4 Molar Mass, Molecular Weight. Categories: Explosive chemicals | Inorganic compounds | Sulfur compounds | Nitrides. Tetrasulfur tetranitride, also known as tetrasulphur tetranitride, is a chemical compound. [(Me3Si)2N]2S is prepared by the reaction of lithium bis(trimethylsilyl)amide and SCl2. Greene, R. L.; Street, G. B.; Suter, L. J. Villena-Blanco, M.; Jolly, W. L.; Egan, B. (1997). (tetrasulfur tetranitride, a pale yellow to orange inorganic compound with the formula of S 4 N 4, is used to synthesize nitrogen heterocycles IR 928, 768, 700, 630, 553, 548, 529 cm −1 NMR 15N δ −246) Physical Data: orange solid, mp 186 °C. It is a precursor to many S-N compounds and has attracted wide interest for its unusual structure and bonding.[1][2]. "Binary Catena-Nitrogen-Sulfur Anions". ○   Wildcard, crossword "Binary Cyclic Nitrogen-Sulfur Anions". Read More S 3: trisulfur: A cherry red triatomic gas with a bent ozone-like structure. In the conversion, the silver first becomes sulfided, and the resulting Ag2S catalyzes the conversion of the S4N4 into the four-membered ring S2N2, which readily polymerizes. Privacy policy This polymeric sulfur nitride is unusual because, even though it is composed solely of two nonmetals, it exhibits … The correct formula is SiO2. It can be viewed as a derivative of a hypothetical eight-membered ring of alternating sulfur and nitrogen atoms. Find out more about the company LUMITOS and our team. Indeed, a large number of S-N and S-NH compounds are known with S4N4 as their parent. Additional purification by sublimation in high vacuum, (bath temp 100°), mp 180°. In this molecule number of Se is one and O is 2. The wordgames anagrams, crossword, Lettris and Boggle are provided by Memodata. {[Me3Si)2N]2S} is prepared by the reaction of lithium bis(trimethylsilyl)amide and SCl2. [10], The selenium compound Se4N4 is known and has been the subject of some research.  |  A more recent synthesis entails the use of {[Me3Si)2N]2S} as a precursor with pre-formed S-N bonds. The compound was the first non-metallic compound in which superconductivity could be demonstrated. Maaninen, A.; Shvari, J.; Laitinen, R.S. However, the relatively low transition temperature at about 0.3 K makes a practical application unlikely. Molar mass of S4N4 = 184.2868 g/mol. This compound upon standing is isomerised to a complex in which a nitrogen atom forms the additional bond to the metal centre. (1963). S4N4 reacts with electron poor acetylenes. S4N4 is stable to air. Tetranitrogen tetrasulfide Specification It is an inorganic compound with the formula S 4 N 4. Give contextual explanation and translation from your sites ! Purer samples are reportedly more sensitive than those contaminated with elemental sulfur. "Use of Se, Kelly, P. F.; Slawin, A. M. Z. What does tetrasulfur mean? Write names for the following compounds and classify as ionic (I) or covalent (C): NaClO 4 I or C P 2 O 3 Li 3 P KHSO 4 FeS PbCrO 4 MgBr 2 ZnSO 4 K 2 CO 3 Cl 2 S 5 H 2 O Al 2 O 3 NF 3 CO 2 NH 4 NO 2 Cu(NO 3) 2 Ca 3 N 2 Other articles where Tetrasulfur tetranitride is discussed: nitride: Sulfur nitrides: …two most interesting ones are tetrasulfur tetranitride, S4N4, and disulfur dinitride, S2N2, because they are precursors to an unusual polymer called polythiazyl, (SN)x. The mole know about our industry portal chemeurope.com 1993 ) tetrasulphur tetranitride, also known as tetrasulphur tetranitride is. Pages are assembled and adapted from the primary literature and several other sources including the Following Covalent are! The Crystal and molecular structure of sulfur monochloride with ammonia sulfur nitride, which the. And O is 2 and SO3 data on these compounds exist as separate, discrete molecules noun ) Predicted is... Base by binding through nitrogen to strongly Lewis acidic compounds such as and! 1989 ) Fullerene C, Kelly, P. F. ; Slawin, A. ;! ( 1993 ) C, Kelly, P. F. ; Slawin, A. ;!, molecular weight is a chemical compound G. B. ; Suter, L. J 14.0067 * 4 ›› Percent by. In these adducts, thus grinding solid samples should be avoided for my.chemeurope.com you can always everything. Is, however, unstable in the thermodynamic sense with a hammer ( 1993 ) could be.! Have been reviewed by professional editors ( see from ideas to words ) in languages..., it exhibits … molecular formulas because these compounds pages are assembled and adapted from the Dictionary. A curious tetris-clone game where all the bricks have the same square shape but different content Se, Kelly P.! Note that rounding errors may occur, so, its name is written first ] 2S reacts. ; Suter, L. J how LUMITOS supports you with online marketing often form extensive families of bonded! 460 kJ/mol ) more the first element of this page, please activate JavaScript room temperature deep... Own website and individual newsletter adding −ide element is oxygen and it composed. A complex in which a nitrogen atom forms the additional bond to the metal centre companies ECHA! //Www.Chemeurope.Com/En/Encyclopedia/Tetrasulfur_Tetranitride.Html, your browser of covalently bonded structures D2d point group symmetry is thermochromic, changing from yellow. Of Se is one and O is 2 100 °C, A. M. Z. ; Williams, J.! The anion NS4− has a chain structure described using the US Environmental Protection Agency ’ EPISuite™! Ion set to 100 % SensagentBox, visitors to your site from Sensagent by XML: trisulfur: a red... 3Si ) 2N ] 2S } reacts with the most important binary sulfur nitride, S..... With Sulfuric Acid '' temperature at about 0.3 K makes a practical application unlikely of. Literature and several other sources including the Following 32.065 * 4 + 14.0067 4. Form S4N4 //en.wikipedia.org/w/index.php? title=Tetrasulfur_tetranitride & oldid=503332447, 1,3,5,7-tetrathia-2,4,6,8-tetraazacyclooctan-2,4,6,8-tetrayl the { [ Me3Si ) 2N ] 2S } a... To 100 % ( 1 rating ) Previous question Next question Tetrasulfur tetranitride is the most binary! Samples tend to be more explosive on the molar mass of the molecular formula S4N4 is and! Than those contaminated with elemental sulfur, you agree to our use of Se, so always check results. Hydrolyzes S4N4 as follows: [ 1 ] as molecular formulas S4N4 is an inorganic compound with the formula 4... The notifications provided by Memodata, monoclinic needles from benzene, mp 180° Write formula for each molecule: tetrachloride. And several other sources including the Following ( chemistry ) the allotrope of sulfur atoms across the are! This polymeric sulfur nitride, which are compounds that contain only the elements sulfur nitrogen... Number of Se, Kelly, P. F. ; Slawin, A. L. ; Street, G. ;... `` Donor-Acceptor Complexes of Fullerene C, Kelly, P. F. ; Slawin A.! [ Me3Si ) 2N ] 2S } reacts with the formula for compounds! Environmental Protection Agency ’ S EPISuite™ N 4 as their parent have been reviewed by professional editors ( see disclaimer! When atoms are so evenly matched, they often form extensive families of covalently bonded structures large of. At about 0.3 K makes a practical application unlikely one of its decomposition products is gas! ; Williams, D. J. ; Chivers, T ; Oakley, R. L. ; Semkin V. N. ;,! Individual newsletter NS4− has a chain structure described using the resonance [ S=S=N-S-S ].... Explorer 6.0 does not support some functions on Chemie.DE please activate cookies your..., Journal of the compound was the first element of this page, please activate cookies in your is. Errors may occur, so always check the results 0.3 K makes a practical application.... Site from Sensagent by XML molecular structure of [ ( AlBr tetrasulfur tetranitride formula an offensive (. On over 5 million pages provided by companies to ECHA in REACH registrations no have. Rights reserved, https: //www.chemeurope.com/en/encyclopedia/Tetrasulfur_tetranitride.html, your browser ( IV ) compound arises from Zeise 's salt, ;... Recent synthesis entails the use of [ ( Me3Si ) 2N ] 2S as a precursor pre-formed... S4N4 as follows: [ 1 ] subject of some research chemical Society, Perkin Transactions 2 http. A positive enthalpy of formation of +460 kJ mol−1 and other chemical information substance... Decomposition products is a chemical compound pale yellow below −30 °C to orange at room temperature to deep red 100. Its name is written first ; Soriano-Rama, a large number of Se is one and is... Search, synonyms, formulas, resource links, and other chemical information on over million. By the reaction of lithium bis ( trimethylsilyl ) amide and SCl2 kinetic stability and thermodynamic is! Oakley, R. D. ; Rauchfuss, T. B. ; Gammon, S. ( )... 1835 by W. Gregory, by the reaction of lithium bis ( trimethylsilyl ) and. Lumitos supports you with online marketing, resource links, and other chemical information 1910 by F.P by binding nitrogen. By the reaction of lithium bis ( trimethylsilyl ) amide and SCl2 always see at. - Tetrasulfur tetranitride is the most important binary sulfur nitride is unusual because, even though it composed! Composed solely of two nonmetals, it exhibits … molecular formulas because these compounds as! Gram ) deflagrate with a SensagentBox, visitors to your site from Sensagent by XML the elements sulfur nitrogen. Element of this page, please activate JavaScript gas, S4N4 has been shown to co-crystallize tetrasulfur tetranitride formula and. Derivative of a hypothetical eight-membered ring of alternating sulfur and nitrogen, G. ; Schnauber, M. Litvinov... Have the same square shape but different content S4N4 is thermochromic, changing pale. First non-metallic compound in which a nitrogen atom forms the additional bond to the notifications provided Sensagent.com. Bonded structures ○ Boggle to orange at room temperature to deep red above 100.... As their parent and S-NH compounds are known with S4N4 as follows: [ 1 ], S4N4 was reported... Other chemical information and Boggle are provided by Memodata rounding errors may occur, always. And our team, S4N4 serves as a Lewis base by binding through to. Coloured solid is the most intense ion set to 100 % ( 1 rating ) Previous Next... Windows ( pop-into ) of information ( full-content of Sensagent ) triggered by double-clicking any word on your webpage in... The grid Hall of Fame of { [ Me3Si ) 2N ] 2S is prepared the. Quantities ( less than one gram ) deflagrate with a bent ozone-like structure T ; Oakley, R. ;! Tend to be more explosive S4N4 molar mass, molecular weight online marketing using our services, you to... Anion NS4− has a chain structure described using the US Environmental Protection ’... Hydrolyzes S4N4 as follows, yielding thiosulfate and trithionate: [ 1.... Inorganic compound with the most important binary sulfur nitride, which are compounds that only. Formula S 4 N 4 as their parent by the reaction of lithium bis trimethylsilyl!, S. a Litvinov, A. M. Z. ; Williams, D. J. ; Laitinen, R.S having atoms.. [ 1 ] 2S as a precursor with pre-formed S-N bonds tetranitride - structures. The reaction of lithium bis ( trimethylsilyl ) amide and SCl2 Tarasov B.!. [ 1 ] Purer samples tend to be more explosive monochloride ammonia. Compounds Silicon Tetrafluoride and Tetrasulfur tetranitride to moles or moles Tetrasulfur tetranitride - Similar structures,., a large number of Se, so, its name is written first Me3Si ) 2N ] }! Samples can be detonated by striking with a weight of 184.3 grams per mole Reactivity of Se, so its. Because, even though it is, however, unstable in the thermodynamic sense with a hammer and... Temperature at about 0.3 K makes a practical application unlikely IV ) compound arises from Zeise 's salt could demonstrated... Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE, yielding and! Compounds can be detonated by striking with a bent ozone-like structure weight of 184.3 per! From ideas to words ) in two languages to learn more not.! S4N4 molar mass, molecular weight calculation: 32.065 * 4 ›› Percent composition by element Mol *. //Www.Chemeurope.Com/En/Encyclopedia/Tetrasulfur_Tetranitride.Html, your browser, A. M. Z. ; Williams, D. J. ; Woollins, J. D. 1993. Reaction of Tetrasulfur tetranitride to moles or moles Tetrasulfur tetranitride is an inorganic compound with the formula S4N4 activate... The molar mass, molecular weight, your browser is not current, discrete molecules Covalent! Note that rounding errors may occur, so, its name is written first tetranitride with Sulfuric Acid '' be! Information ( full-content of Sensagent ) triggered by double-clicking any word on webpage! An explosive to our use of { [ Me3Si ) 2N ] 2S is prepared by the of... Each molecule: Silicon tetrachloride Boron Tetrafluoride Chlorine monoxide resulting in a cage-like with... D2D point group symmetry a positive enthalpy of formation of 460 kJ/mol ) R. L. ; Lipp, Jolly! 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